Enhanced Photodegradation of Rhodamine B Using Visible-Light Sensitive N-TiO2/rGO Composite
نویسندگان
چکیده
Rhodamine B (RhB) is extensively used for dyeing purposes, and cannot be completely removed using traditional water treatment technologies. Here, we report the first time photodegradation of RhB nitrogen-doped titanium dioxide (N-TiO2) on reduced graphene oxide (rGO) composite (N-TiO2/rGO). The work primarily highlights synergistic effect incorporation N-TiO2 rGO its kinetic study RhB. N-TiO2/rGO was synthesized by dispersing titanium(IV) isopropoxide urea, followed annealing via hydrothermal method with rGO. Scanning electron microscopy (SEM) images illustrated that particles an irregular round shape white color were dispersed onto surface. X-Ray diffraction (XRD) patterns revealed showed anatase phase TiO2 a peak 2? = 25.622°. gas sorption analysis (GSA) had surface area, pore volume, size 53.393 m2/g, 0.096 cc/g, 3.588 nm, respectively. thermogravimetric-differential thermal (TG-DTA) appeared at temperature 200–500 °C, weight loss 2.50%. According to ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS) study, TiO2, N-TiO2, band gap energies 3.25, 2.95, 2.86 eV, highest obtained optimum condition in pH 2 photocatalyst mass 20 mg irradiation 90 min. photocatalytic activity visible light higher percentage 78.29%, compared 44.08% under UV light. pseudo-second-order model.
منابع مشابه
Detection of intermediates in the TiO2-assisted photodegradation of Rhodamine B under visible light irradiation.
The photocatalytic degradation of dye Rhodamine B (RhB) in the presence of TiO2 nanostripe or P25 under visible light irradiation was investigated. The degradation intermediates were identified using Infrared spectra (IR spectra), 1H nuclear magnetic resonance (1HNMR) spectra, and gas chromatography-mass spectroscopy (GC-MS). The IR and the 1HNMR results showed that the large conjugated chromop...
متن کاملPhotodegradation of Rhodamine B over Biomass-Derived Activated Carbon Supported CdS Nanomaterials under Visible Irradiation
A family of new composite materials was successfully prepared through the deposition of as-synthesized CdS nanomaterials on lotus-seedpod-derived activated carbon (SAC). The SAC supports derived at different activation temperatures exhibited considerably large surface areas and various microstructures that were of great importance in enhancing photocatalytic performance of CdS@SAC composite mat...
متن کاملTaguchi optimization of photodegradation of yellow water of trinitrotoluene production catalyzed by nanoparticles TiO2/N under visible light
Taguchi experimental design technique was used for optimization of photodegradation of yellow water sample of trinitrotoluene (TNT) production process. The nanoparticles of doped N-TiO2 were also used as photocatalysts in the photodegradation reaction under visible light. The ranking of data based on signal to noise ratio values showed that the importance order of the factors affecti...
متن کاملSynthesis of Ag3PO4/G-C3N4 Composite with Enhanced Photocatalytic Performance for the Photodegradation of Diclofenac under Visible Light Irradiation
A new visible-light-driven heterojunction Ag3PO4/g-C3N4 was prepared by a simple deposition-precipitation method for the degradation analysis of diclofenac (DCF), a model drug component, under visible-light irradiation. The heterojunction photocatalysts were characterized by a suite of tools. The results revealed that the introduction of Ag3PO4 on the surface of g-C3N4 greatly promoted its stab...
متن کاملTaguchi optimization of photodegradation of yellow water of trinitrotoluene production catalyzed by nanoparticles TiO2/N under visible light
Taguchi experimental design technique was used for optimization of photodegradation of yellow water sample of trinitrotoluene (TNT) production process. The nanoparticles of doped N-TiO2 were also used as photocatalysts in the photodegradation reaction under visible light. The ranking of data based on signal to noise ratio values showed that the importance order of the factors affecti...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Crystals
سال: 2023
ISSN: ['2073-4352']
DOI: https://doi.org/10.3390/cryst13040588